| Formula |
CAS |
| C19H38N2O3 |
61789-40-0 |
Background
Cocamidopropyl betaine (CAPB) is an increasingly used surfactant in shampoos, detergents, and cleansing lotions. CAPB is an alkylamidobetaine and functions as an amphoteric surfactant with anionic and cationic properties depending on pH. Betaines are less foaming than other surfactants and are expensive; however, they are relatively gentle to the skin, have a low potential to irritate the eyes, have good conditioning characteristics, and have antibacterial activity. A number of cases of contact allergy to CAPB has been reported in the past several years. In 1200 consecutive patch-test clinic patients, 46 patients (3.8%) had allergic reactions.
3-dimethylaminopropylamine (DMAPA), an aliphatic amine used to synthesize CAPB, has been reported to be the responsible allergen in the CAPB reactions (Angelini et al; Pigatto et al).
Related compound: lauryl hydroxysultaine (SHD), synonyme: Cocoamidopropyl Hydroxy Sulfo Betaine (CHSB), Formula:
RCONH (CH2)3N+(CH3)2CH2CH(OH)CH2SO3- R: Coco, CAS-nr: 86438-79-1.
SynonymsTegobetaine L7
N-Cocamidopropyl-N,N-dimethylglycine inner salt
N-(3-Cocoamidopropyl)-betaine
CAPB
Cocoyl amide propyldimethyl glycine
Coconut oil amidopropyl betaine
UsesAnal detergent
Bath formulations
Contact lens cleaning solutions
Creams
Deodorants
Eye make-up removers
Hair colorants and styling products
Liquid soaps
Shampoos
Shaving products
Toothpastes
Cross-ReactionsCocobetaine
Triethanolamine
Polyethylene glycol cocamide sulfate
3-dimethylaminopropylamine
Unusual Reactions
Back to list of contact allergens
Referenties
| 1. |
Andersen KE, Roed-Petersen J, Kamp P.
Contact allergy related to TEA-PEG-3 cocamide sulfate and
cocamidopropyl betaine in a shampoo. Contact Dermatitis
1984;11(3):192-193. |
| 2. |
Cameli N. et al. Eyelid dermatitis due
to cocamidopropyl betaine in a hard contact lens solution.
Contact Dermatitis 1991;25(4):261-262. |
| 3. |
Ross JS, White IR. Eyelid dermatitis due
to cocamidopropyl betaine in an eye make-up remover. Contact
Dermatitis 1991;25(1):64. |
| 4. |
Korting HC. et al. Allergic contact
dermatitis to cocamidopropyl betaine in shampoo. Journal of the
American Academy of Dermatology 1992;27(6 Pt 1):1013-1015. |
| 5. |
Peter C, Hoting E. Contact allergy to
cocamidopropyl betaine (CAPB). Contact Dermatitis
1992;26(4):282-283. |
| 6. |
Taniguchi S. et al. Shampoo dermatitis
due to cocamidopropyl betaine. Contact Dermatitis
1992;26(2):139. |
| 7. |
van der Walle HB, Brunsveld VM.
Dermatitis in hairdressers. (I). The experience of the past 4
years. Contact Dermatitis 1994;30(4):217-221. |
| 8. |
Pigatto P, Bigardi A, Cusano F. Contact
dermatitis to cocamidopropylbetaine is caused by residual
amines: Relevance, clinical characteristics, and review of the
literature. American Journal of Contact Dermatitis
1995;6(1):13-16. |
Author(s):Allergology: background information on allergens.